Iron and Copper Complexes of Tetraphenyl-m-benziporphyrin:  Reactivity of the Internal C−H Bond

Iron and copper complexes of tetraphenyl-m-benziporphyrin (TPmBPH)H have been prepared and structurally characterized. The iron system, (TPmBPH)FeIIBr, contains a high-spin Fe(II) center. In the solid state the complex forms dimeric units linked by weak CH···Br hydrogen bonds. The Cu complex contain...

Full description

Saved in:
Bibliographic Details
Published in:Inorganic chemistry 2004-07, Vol.43 (14), p.4118-4120
Main Authors: Hung, Chen-Hsiung, Chang, Fei-Chien, Lin, Cheng-Yu, Rachlewicz, Krystyna, Stȩpień, Marcin, Latos-Grażyński, Lechosław, Lee, Gene-Hsiang, Peng, Shie-Ming
Format: Article
Language:English
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:Iron and copper complexes of tetraphenyl-m-benziporphyrin (TPmBPH)H have been prepared and structurally characterized. The iron system, (TPmBPH)FeIIBr, contains a high-spin Fe(II) center. In the solid state the complex forms dimeric units linked by weak CH···Br hydrogen bonds. The Cu complex contains a tetrameric copper cluster with a Cu2Cl4 2- unit bridging two [(TPmBPCl)CuII]+ fragments. The formation of (TPmBPCl)H represents an example of copper-catalyzed chlorination on the internal carbon atom of (TPmBPH)H.
ISSN:0020-1669
1520-510X
DOI:10.1021/ic049821l