Iron and Copper Complexes of Tetraphenyl-m-benziporphyrin:  Reactivity of the Internal C−H Bond

Iron and copper complexes of tetraphenyl-m-benziporphyrin (TPmBPH)H have been prepared and structurally characterized. The iron system, (TPmBPH)FeIIBr, contains a high-spin Fe(II) center. In the solid state the complex forms dimeric units linked by weak CH···Br hydrogen bonds. The Cu complex contain...

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Published in:Inorganic chemistry 2004-07, Vol.43 (14), p.4118-4120
Main Authors: Hung, Chen-Hsiung, Chang, Fei-Chien, Lin, Cheng-Yu, Rachlewicz, Krystyna, Stȩpień, Marcin, Latos-Grażyński, Lechosław, Lee, Gene-Hsiang, Peng, Shie-Ming
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cited_by cdi_FETCH-LOGICAL-a412t-591561173eabae02a8a12d8852c710c4b6ef041a3da25a777b33a9e0588c961a3
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container_end_page 4120
container_issue 14
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container_title Inorganic chemistry
container_volume 43
creator Hung, Chen-Hsiung
Chang, Fei-Chien
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Rachlewicz, Krystyna
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Latos-Grażyński, Lechosław
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Peng, Shie-Ming
description Iron and copper complexes of tetraphenyl-m-benziporphyrin (TPmBPH)H have been prepared and structurally characterized. The iron system, (TPmBPH)FeIIBr, contains a high-spin Fe(II) center. In the solid state the complex forms dimeric units linked by weak CH···Br hydrogen bonds. The Cu complex contains a tetrameric copper cluster with a Cu2Cl4 2- unit bridging two [(TPmBPCl)CuII]+ fragments. The formation of (TPmBPCl)H represents an example of copper-catalyzed chlorination on the internal carbon atom of (TPmBPH)H.
doi_str_mv 10.1021/ic049821l
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title Iron and Copper Complexes of Tetraphenyl-m-benziporphyrin:  Reactivity of the Internal C−H Bond
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