Synthesis and Electrical Characterization of Oligo(phenylene ethynylene) Molecular Wires Coordinated to Transition Metal Complexes

• Published in: ACS nano 2009-08, Vol.3 (8), p.2103-2114
• Main Authors: Ng, Zhaoyue, Loh, Kian Ping, Li, Liqian, Ho, Peter, Bai, Ping, Yip, John H. K
• Format: Article
• Language: English
• ISSN: 1936-0851; 1936-086X
• DOI: 10.1021/nn900570v

Organometallic wires are interesting alternatives to conventional molecular wires based on a pure organic system because of the presence of d orbitals in the transition metal complex. However, synthetic problems, such as decreased stability of the compounds when labile metal complexes are present, often impede their isolation in a pure state and preclude a rapid development of such hybrid molecular wires. In this work, we show that preassembled self-assembled monolayers (SAM) based on pyridine-terminated 1-((4-acetylthiophenyl)ethynyl)-4-((4-pyridyl)ethynyl)benzene can act as a template for the architectural build up of a second layer of transition metal complexes to form an array of organometallic molecular wires on gold. RuII(terpy)(bipy)2+ (terpy = 2,2′:6′,2′′-terpyridine and bipy = 2,2′-bipyridine) or cyclometalated PtII(pbipy) (pbipy = 6-phenyl-2,2′-bipyridine) were axially coordinated onto the organic SAM via its terminal pyridinium moieties. Current−voltage studies show that the electronic coupling between the transition metal and organic wire produces a molecular wire that exhibits higher conductance than the original organic chain. The presence of the transition metal complexes in the hybrid molecular wire introduces distinctive negative differential resistance (NDR) effects.