Two-directional synthesis and stereochemical assignment toward a C2 symmetric oxasqualenoid (+)-intricatetraol

The asymmetric synthesis of tetraol (+)-3, a degradation product derived from a C2 symmetric oxasqualenoid intricatetraol 1, has been achieved through the two-directional synthesis starting from diol 7, realizing the further additional assignment of the incomplete stereostructure of 1, the stereoche...

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Bibliographic Details
Published in:Organic & biomolecular chemistry 2006-09, Vol.4 (17), p.3220-3222
Main Authors: Morimoto, Yoshiki, Takaishi, Mamoru, Adachi, Noriko, Okita, Tatsuya, Yata, Hiromi
Format: Article
Language:English
Subjects:
Alcohols - chemical synthesis
Alcohols - chemistry
Epoxy Compounds - chemical synthesis
Epoxy Compounds - chemistry
Models, Molecular
Molecular Conformation
Squalene - analogs & derivatives
Squalene - chemical synthesis
Squalene - chemistry
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Summary:The asymmetric synthesis of tetraol (+)-3, a degradation product derived from a C2 symmetric oxasqualenoid intricatetraol 1, has been achieved through the two-directional synthesis starting from diol 7, realizing the further additional assignment of the incomplete stereostructure of 1, the stereochemistry of which is difficult to determine otherwise.
ISSN:1477-0520
1477-0539
DOI:10.1039/b608098g