Correcting Nonlinear Response of Mercury Cadmium Telluride Detectors in Open Path Fourier Transform Infrared Spectrometry

• Published in: Analytical chemistry (Washington) 2008-07, Vol.80 (13), p.5219-5224
• Main Authors: Shao, Limin, Griffiths, Peter R
• Format: Article
• Language: English
• Subjects: Analytical chemistry; Chemistry; Exact sciences and technology; Fourier analysis; Fourier transforms; Mercury cadmium telluride; Scientific imaging; Spectrometric and optical methods
• ISSN: 0003-2700; 1520-6882
• DOI: 10.1021/ac800522w

The effect of a nonlinear response of mercury cadmium telluride (MCT) detectors to photon flux is to cause a large offset and a slow variation in the zero-line of single-beam Fourier transform infrared (FT-IR) spectra, which dramatically reduce the accuracy to which strongly absorbing bands or lines can be measured. We describe a noniterative numerical technique by which the baseline offset can be corrected by adjusting the values of the maximum point in the interferogram (the “centerburst”) and the points on either side. The technique relies on the presence of three spectral regions at which the signal is known to be zero. Two of these are found in all spectra, namely, the region below the detector cutoff and the high-wavenumber region just below the Nyquist wavenumber where the interferogram has been electronically filtered. In open path FT-IR measurements there are several regions where atmospheric water vapor and CO2 are totally opaque. We have selected the region around 3750 cm−1. This algorithm is even shown to work well when the interferogram is clipped, i.e., the value at the centerburst exceeds the dynamic range of the analog-to-digital converter.