Spectroscopic and computational evidence for SO2 ionization on 128 K ice surface

• Published in: Physical chemistry chemical physics : PCCP 2008-01, Vol.10 (32), p.4678-4684
• Main Authors: Jagoda-Cwiklik, B, Devlin, J P, Buch, V
• Format: Article
• Language: English
• ISSN: 1463-9076; 1463-9084
• DOI: 10.1039/b809839p

The experimental part of this study focuses on FTIR spectroscopy of SO(2) adsorbate on the surface of ice nanoparticles at 128 K, in the 0.5-1 monolayer coverage range. In addition to the infrared spectroscopic features due to molecular SO(2), a structured band is observed at approximately 1030 cm(-1). A similar band was observed in past spectroscopic studies of SO(2) aqueous solutions, and assigned to anionic products of SO(2) ionization. Ab initio normal mode analysis of HSO(3)(-) yielded intense SO stretch bands in the vicinity of the observed "ionic" feature. The relative intensities of the molecular and the anionic bands indicate that 0.3 approximately 0.5 of the adsorbate is ionized. These results are consistent with the previously published data on isotopic exchange in SO(2)-covered ice nanoparticles (Devlin and Buch, J. Chem. Phys., 2007, 127, 091101) which pointed towards substantial SO(2) ionization at low temperatures. Density functional theory modeling of molecular and ionized adsorbate on a crystal ice slab suggests that anion solvation by molecular SO(2) adsorbate facilitates the SO(2) ionization process at the ice surface.