Boronyls as Key Structural Units in Boron Oxide Clusters:  B(BO)2 - and B(BO)3

Even though BO- is isoelectronic with CN-, the chemistry of BO- is relatively unknown. Here we report the first combined photoelectron spectroscopy and computational evidence that BO is a robust inorganic ligand that governs structural and electronic properties in B3O2 - and B4O3 -. Both anions yiel...

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Bibliographic Details
Published in:Journal of the American Chemical Society 2007-08, Vol.129 (30), p.9254-9255
Main Authors: Zhai, Hua-Jin, Li, Si-Dian, Wang, Lai-Sheng
Format: Article
Language:English
Subjects:
BORON OXIDES
ELECTRONIC STRUCTURE
Environmental Molecular Sciences Laboratory
INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY
MOLECULAR CLUSTERS
MOLECULAR STRUCTURE
PHOTOELECTRON SPECTROSCOPY
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