A System for the Direct Determination of the Nonvolatile Organic Carbon, Dissolved Organic Carbon, and Inorganic Carbon in Water Samples through Inductively Coupled Plasma Atomic Emission Spectrometry

• Published in: Analytical chemistry (Washington) 2003-01, Vol.75 (1), p.111-117
• Main Authors: Maestre, S. E, Mora, J, Hernandis, V, Todolí, J. L
• Format: Article
• Language: English
• Subjects: Analysis methods; Analytical chemistry; Applied sciences; Calibration; Carbon - analysis; Carbon - chemistry; Carbon Dioxide - analysis; Chemistry; Exact sciences and technology; Natural water pollution; Pollution; Sensitivity and Specificity; Spectrometric and optical methods; Spectrophotometry - instrumentation; Spectrophotometry - methods; Volatilization; Water - chemistry; Water treatment and pollution
• ISSN: 0003-2700; 1520-6882
• DOI: 10.1021/ac025980f

A new system has been developed for the determination of total organic carbon (TOC) and inorganic carbon (IC) or total inorganic carbon (TIC) in waters. Only nonvolatile organic compounds can be detected through the present method. The system presented in this work is based on the measurement of the carbon atomic emission intensity in inductively coupled plasma atomic emission spectrometry (ICP-AES). This way, the organic matter does not undergo any preoxidation step. A semiautomatic accessory connected to the spectrometer separates the different carbon fractions (i.e., organic and inorganic). Because most of the solutions used in the present work did not contain suspended solid particles, the actual parameter that was determined was the dissolved organic carbon (DOC). The present system exhibits good sensitivities compared to those provided by conventional TOC and IC determination methods. The limits of detection obtained in the present work have been 0.07 and 0.0007 mg/L C in terms of TOC and IC, respectively. Furthermore, the system is able to handle high-salt-content solutions. This fact suggests that it would be possible to analyze seawater samples, avoiding some of the problems encountered with conventional methods, such as system blocking or interferences. The TOC and IC values found for natural samples are very close to those measured using conventional methods. The ICP-AES method has been successfully used in two interesting applications:  (i) monitoring the efficiency of a water treatment plant and (ii) determining the contents of dissolved carbon dioxide, on one hand, and that of carbonate and bicarbonate, on the other, in the same sample.