Determination of fast ozone oxidation rate for textile dyes by using a continuous quench-flow system

• Published in: Journal of hazardous materials 2010-06, Vol.178 (1), p.57-65
• Main Authors: Gomes, Arlindo C., Nunes, José C., Simões, Rogério M.S.
• Format: Article
• Language: English
• Subjects: Anthraquinones - chemistry; Applied sciences; Azo; Azo Compounds - chemistry; Chemical engineering; Coloring Agents - chemistry; Dyes; Exact sciences and technology; Free Radical Scavengers - chemistry; Hydrogen-Ion Concentration; Hydroxyl Radical; Kinetics; Oxidation-Reduction; Ozone; Ozone - chemistry; Pollution; Potassium iodides; Quench-flow system; Radicals; Reactors; Scavengers; tert-Butyl Alcohol - chemistry; Textile dyes; Textiles; Textiles - analysis
• ISSN: 0304-3894; 1873-3336
• DOI: 10.1016/j.jhazmat.2010.01.043

To study the fast kinetic decolourisation of textile dyes by ozone a continuous quench-flow system was used. This system has not been used before for these purposes. Reaction times in the range of 7–3000 ms were explored. The reaction was quenched with potassium iodide, which proved to be very effective, and the indigo method was used to follow the ozone concentration. Dyes from the most representative chemical classes currently used in the textile industry, i.e. azo and anthraquinone, were selected. Using the initial slope method, the effect of dye and ozone concentrations was researched and the kinetic equations thus established. Using tert-butyl alcohol, as radical scavenger, and pH close to 2.5, the second-order rate constant of the reactant dyes at 280 K varies in the range of 1.20 × 10 4–7.09 × 10 5 M −1 s −1; the Acid Orange 7 exhibiting thus its lowest value, the Acid Blue 45 its highest value and the Acid Green 25 and 27 and Direct Yellow 4 intermediate values (≈1.6 × 10 5 M −1 s −1). Without radical scavenger and the pH close to 4, the reaction rate increases one order of magnitude, but, on the reverse, the efficiency of ozone to decolourisation decreases.