H2S and O2 influence on the corrosion of carbon steel immersed in a solution containing 3M diethanolamine

Aqueous solutions with 3molLa degree 1 (M) diethanolamine (DEA) concentration are extensively used in the gas processing industry to remove acid gases. However, the degradation of the DEA and the formation of heat-stable salts (HSS) lead to severe corrosion problems. Even worse, equipment corrosion...

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Bibliographic Details
Published in:Corrosion science 2010-07, Vol.52 (7), p.2268-2279
Main Authors: Garcia-Arriaga, V., Alvarez-Ramirez, J., Amaya, M., Sosa, E.
Format: Article
Language:English
Subjects:
Carbon steels
Corrosion
Crude oil
Degradation
Diethanolamines
Dissolution
Iron and steel plants
Natural gas
Sulfides
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Summary:Aqueous solutions with 3molLa degree 1 (M) diethanolamine (DEA) concentration are extensively used in the gas processing industry to remove acid gases. However, the degradation of the DEA and the formation of heat-stable salts (HSS) lead to severe corrosion problems. Even worse, equipment corrosion can be magnified by the unavoidable presence of sulphide acid and dissolved oxygen as a result of hydrocarbon (natural gases and crude oil) processing. The aim of this work is to study the combined corrosion effects of DEA, sulphide acid and oxygen on carbon steel. Electrochemical methods revealed that in the 3M DEA medium without oxygen, corrosion processes are modulated by adsorbed DEA film formation. Furthermore, it was shown that the addition of oxygen and 15A-10a degree 3 molLa degree 1 (15mM) H2S produced the formation of an adherent film on the carbon steel surface. Chemical analyses by EDAX revealed a homogeneous film of corrosion products composed of iron oxide and sulphide formed in DEA solution containing O2 and H2S, respectively. Equivalent circuits were used to estimate the parameters associated with ion diffusion through the formed corrosion films. The results showed that the presence of H2S induced the formation of thin iron sulphide films that provide protective properties to the metal. It is concluded that the presence of oxygen in a sweetening plant should be avoided as DEA degradation can be produced with the subsequent decrease in chelating process efficiency and the increase in corrosion problems.
ISSN:0010-938X
DOI:10.1016/j.corsci.2010.03.016