Thermodynamic and kinetic investigations of phosphate adsorption onto hydrous niobium oxide prepared by homogeneous solution method

The adsorption kinetics of phosphate onto Nb 2O 5·nH 2O was investigated at initial phosphate concentrations 10 and 50 mg L − 1. The kinetic process was described by a pseudo second-order rate model very well. The adsorption thermodynamics was carried out at 298, 308, 318, 328 and 338 K. The positiv...

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Bibliographic Details
Published in:Desalination 2010-11, Vol.263 (1), p.29-35
Main Authors: Rodrigues, Liana Alvares, da Silva, Maria Lúcia Caetano Pinto
Format: Article
Language:English
Subjects:
Adsorption
Applied sciences
Bending vibration
Chemical engineering
Desorption
Exact sciences and technology
Isotherms
Kinetic
Mathematical models
Phosphate
Phosphates
Pollution
Reaction kinetics
Spectra
Thermodynamic
Thermodynamics
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Summary:The adsorption kinetics of phosphate onto Nb 2O 5·nH 2O was investigated at initial phosphate concentrations 10 and 50 mg L − 1. The kinetic process was described by a pseudo second-order rate model very well. The adsorption thermodynamics was carried out at 298, 308, 318, 328 and 338 K. The positive values of both ΔH and ΔS suggest an endothermic reaction and increase in randomness at the solid–liquid interface during the adsorption. ΔG values obtained were negative indicating a spontaneous adsorption process. The Langmuir model described the data better than the Freundlich isotherm model. The peak appearing at 1050 cm − 1 in IR spectra after adsorption was attributed to the bending vibration of adsorbed phosphate. The effective desorption could be achieved using water at pH 12.
ISSN:0011-9164
1873-4464
DOI:10.1016/j.desal.2010.06.030