Microstructural and physical properties of silica aerogels based on oil shale ash

• Published in: Powder technology 2010-08, Vol.202 (1), p.137-142
• Main Authors: Gao, Gui-Mei, Xu, Xue-Chun, Zou, Hai-Feng, Ji, Gui-Juan, Gan, Shu-Cai
• Format: Article
• Language: English
• Subjects: Applied sciences; Chemical engineering; Exact sciences and technology; Mesoporous materials; Miscellaneous; Oil shale ash; Silica aerogels; Solid-solid systems; Surface modification agents
• ISSN: 0032-5910; 1873-328X
• DOI: 10.1016/j.powtec.2010.04.028

The silica aerogels based on oil shale ash were successfully synthesized in the presence of different surface modification agents via ambient pressure drying. The organic modification of hydrogels was a crucial step during the processing which preserved mesopores in ambient pressure drying. It was found that the textural properties of silica aerogels dependent on the type of surface modification agents. The hexamethyldisilazane (HMDZ) modified aerogels had much lower tapping density (0.084 cm 3), higher specific surface area (980 m 2/g) and larger cumulative pore volume (2.42 cm 3/g) and higher porosity (96.16%) than those of dimethyldichlorosilane (DMDC) and trimethylchlorosilane (TMCS) modified aerogels. The HMDZ modified aerogel exhibited a narrow pore size distribution and small average pore size, while DMDC and TMCS modified aerogels had relatively wider pore size distributions, bigger average pore sizes and lower porosity. The FT-IR analysis indicated that as the number of alkyl groups present in surface modification agents increased, the intensity of the peaks related to –OH at 3500 and 1600 cm − 1 decreased (HMDZ < TMCS < DMDC).The TG–DTA analysis revealed that all the surface-modified aerogels were found to be thermally stable up to a temperature of 350 °C, the HMDZ and TMCS modified aerogels showed higher thermal stability (∼ 400 °C). The silica aerogels based on oil shale ash were successfully synthesized in the presence of different surface modification agents via ambient pressure drying. The hexamethyldisilazane (HMDZ) modified aerogels had much lower tapping density, higher specific surface area and larger cumulative pore volume than those of dimethyldichlorosilane (DMDC) and trimethylchlorosilane (TMCS) modified aerogels. [Display omitted]