Lock-exchange experiments with an autocatalytic reaction front

• Published in: The Journal of chemical physics 2010-12, Vol.133 (24), p.244505-244505-8
• Main Authors: Malham, I. Bou, Jarrige, N., Martin, J., Rakotomalala, N., Talon, L., Salin, D.
• Format: Article
• Language: English
• ISSN: 0021-9606; 1089-7690
• DOI: 10.1063/1.3507899

A viscous lock-exchange gravity current corresponds to the reciprocal exchange of two fluids of different densities in a horizontal channel. The resulting front between the two fluids spreads as the square root of time, with a diffusion coefficient reflecting the buoyancy, viscosity, and geometrical configuration of the current. On the other hand, an autocatalytic reaction front between a reactant and a product may propagate as a solitary wave, namely, at a constant velocity and with a stationary concentration profile, resulting from the balance between molecular diffusion and chemical reaction. In most systems, the fluid left behind the front has a different density leading to a lock-exchange configuration. We revisit, with a chemical reaction, the classical situation of lock-exchange. We present an experimental analysis of buoyancy effects on the shape and the velocity of the iodate arsenous acid autocatalytic reaction fronts, propagating in horizontal rectangular channels and for a wide range of aspect ratios (1/3 to 20) and cylindrical tubes. We do observe stationary-shaped fronts, spanning the height of the cell and propagating along the cell axis. Our data support the contention that the front velocity and its extension are linked to each other and that their variations scale with a single variable involving the diffusion coefficient of the lock-exchange in the absence of chemical reaction. This analysis is supported by results obtained with lattice Bathnagar-Gross-Krook (BGK) simulations Jarrige [Phys. Rev. E 81 , 06631 (2010)], in other geometries (like in 2D simulations by Rongy [J. Chem. Phys. 127 , 114710 (2007)] and experiments in cylindrical tubes by Pojman [J. Phys. Chem. 95 , 1299 (1991)]), and for another chemical reaction Schuszter [Phys. Rev. E 79 , 016216 (2009)].