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Enantio- and Regioselective Iridium-Catalyzed Allylic Hydroxylation
The first enantioselective allylic hydroxylation to prepare branched allylic alcohols directly is described. Bicarbonate was used as nucleophile in conjunction with new single component Ir-catalysts, which are stable to air and water. Excellent regio- and enantioselectivities have been achieved with...
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Published in: | Journal of the American Chemical Society 2011-02, Vol.133 (7), p.2072-2075 |
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Main Authors: | , , , |
Format: | Article |
Language: | English |
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cited_by | cdi_FETCH-LOGICAL-a380t-5d1373163e018ad2a7c27237c7ef33800fdff81a4021db9ecca90716cd7ff1213 |
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cites | cdi_FETCH-LOGICAL-a380t-5d1373163e018ad2a7c27237c7ef33800fdff81a4021db9ecca90716cd7ff1213 |
container_end_page | 2075 |
container_issue | 7 |
container_start_page | 2072 |
container_title | Journal of the American Chemical Society |
container_volume | 133 |
creator | Gärtner, Martin Mader, Steffen Seehafer, Kai Helmchen, Günter |
description | The first enantioselective allylic hydroxylation to prepare branched allylic alcohols directly is described. Bicarbonate was used as nucleophile in conjunction with new single component Ir-catalysts, which are stable to air and water. Excellent regio- and enantioselectivities have been achieved with a representative set of substrates. |
doi_str_mv | 10.1021/ja109953v |
format | article |
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language | eng |
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source | American Chemical Society:Jisc Collections:American Chemical Society Read & Publish Agreement 2022-2024 (Reading list) |
title | Enantio- and Regioselective Iridium-Catalyzed Allylic Hydroxylation |
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