Improved spreading rates for monolayers applied as emulsions to reduce water evaporation

• Published in: Journal of colloid and interface science 2011-05, Vol.357 (1), p.239-242
• Main Authors: Herzig, M.A., Barnes, G.T., Gentle, I.R.
• Format: Article
• Language: English
• Subjects: Chemistry; Colloidal state and disperse state; Emulsifiers; Emulsifying agents; Emulsion application; Emulsions; Emulsions. Microemulsions. Foams; Evaporation; evaporation rate; Evaporation reduction; Exact sciences and technology; General and physical chemistry; Langmuir monolayers; Materials selection; Monolayers; nonionic surfactants; polysorbates; Spreading; Spreads; Surface physical chemistry; Surface pressure; Water evaporation
• ISSN: 0021-9797; 1095-7103
• DOI: 10.1016/j.jcis.2011.01.071

Emulsion spreading can be used to spread evaporation retarding monolayers very quickly. With careful choice of emulsifier such monolayers maintain good evaporation resistance. [Display omitted] ► Using emulsions to apply monolayers can dramatically raise spreading rate over powder application. ► The choice of emulsifier is critical for effective evaporation resistance. ► This work enables the use of monolayer materials that otherwise spread too slowly. To be suitable for reducing water evaporation, monolayers need to be easy to apply and also spread quickly across the surface of water. However, the choice of monolayer often involves a compromise between spreading rate and evaporation resistance. Because emulsions of the monolayer material have been suggested as a way to improve spreading, emulsions were made with the long-chain alcohols hexadecanol, octadecanol and eicosanol using the non-ionic surfactants Brij 78 and Tween 60 as emulsifying agents. The emulsions of octadecanol and eicosanol spread faster than the corresponding powder. However there was no improvement in the spreading of hexadecanol emulsion due to a significant amount of the material dispersing into the bulk water instead of spreading at the interface. The choice of emulsifier to stabilise the emulsions is critical for effective evaporation resistance. Whereas the octadecanol emulsion made with Brij 78 showed improved evaporation resistance, the emulsion with Tween 60 had an appreciably lower evaporation resistance than powdered octadecanol. One limitation of the emulsion application method is the poor spreading on surfaces with an already high surface pressure.