A comparative investigation on adsorption performances of mesoporous activated carbon prepared from waste rubber tire and activated carbon for a hazardous azo dye—Acid Blue 113

• Published in: Journal of hazardous materials 2011-02, Vol.186 (1), p.891-901
• Main Authors: Gupta, V.K., Gupta, Bina, Rastogi, Arshi, Agarwal, Shilpi, Nayak, Arunima
• Format: Article
• Language: English
• Subjects: Acid Blue 113; Activated carbon; Adsorbents; Adsorption; Adsorption isotherm; Adsorption kinetics; Applied sciences; Azo; Azo Compounds - chemistry; Azo Compounds - toxicity; azo dyes; Carbon - chemistry; chemical analysis; Chemical engineering; Desorption; Diffusion; Dyes; Exact sciences and technology; Fourier transform infrared spectroscopy; Hydrogen-Ion Concentration; Kinetics; Mathematical models; Microscopy, Electron, Scanning; Particle Size; Pollution; porosity; Rubber; scanning electron microscopy; sodium hydroxide; sorption isotherms; surface area; Surface chemistry; Temperature; thermodynamics; Tires; Waste rubber tire
• ISSN: 0304-3894; 1873-3336
• DOI: 10.1016/j.jhazmat.2010.11.091

[Display omitted] ▶ The system is cheap, efficient and fast for the removal of dyes from waters. ▶ Higher adsorption capacity is due to higher mesoporous volume of the adsorbent. ▶ The rate determining step of the adsorption process is particle diffusion. A mesoporous carbon developed from waste tire rubber, characterized by chemical analysis, FTIR, and SEM studies, was used as an adsorbent for the removal and recovery of a hazardous azo dye, Acid Blue 113. Surface area, porosity, and density were determined. The adsorption of the dye over the prepared adsorbent and a commercial activated carbon was achieved under different pH, adsorbate concentration, sieve size, adsorbent dosage, contact time and temperature conditions. Langmuir and Freundlich adsorption isotherm models were applied and thermodynamic parameters were calculated. Kinetic studies indicated that the adsorption process follow first order kinetics and particle diffusion mechanisms are operative. By percolating the dye solution through fixed-bed columns the bulk removal of the Acid Blue 113 was carried out and necessary parameters were determined to find out the percentage saturation of both the columns. Recovery of the dye was made by eluting 0.1M NaOH through the column.