A simple approach for immobilization of gold nanoparticles on graphene oxide sheets by covalent bonding

• Published in: Applied surface science 2011-02, Vol.257 (8), p.3350-3357
• Main Authors: Pham, Tuan Anh, Choi, Byung Choon, Lim, Kwon Taek, Jeong, Yeon Tae
• Format: Article
• Language: English
• Subjects: Bonding; Chlorides; Condensed matter: electronic structure, electrical, magnetic, and optical properties; Condensed matter: structure, mechanical and thermal properties; Covalent immobilization; Cross-disciplinary physics: materials science; rheology; Exact sciences and technology; Functionalization; Gold; Gold nanoparticles; Graphene; Graphene oxide; Hybrid material; Immobilization; Nanoparticles; Oxides; Physics; Scanning electron microscopy
• ISSN: 0169-4332; 1873-5584
• DOI: 10.1016/j.apsusc.2010.11.023

▶ The surface functionalization of gold nanoparticles obtanied using 4-aminothiophenol through Au-S chemistry. ▶ The functionalized gold nanoparticles were well immobilized on the graphene oxide surface via amide bonding. ▶ The resulting novel hybrid was investigated in detail using various techniques. Amino—functionalized gold nanoparticles with a diameter of around 5nm were immobilized onto the surface of graphene oxide sheets (GOS) by covalent bonding through a simple amidation reaction. Pristine graphite was firstly oxidized and exfoliated to obtain GOS, which further were acylated with thionyl chloride to give acyl chloride bound GOS. Gold nanoparticles (AuNPs) were functionalized using 4-aminothiophenol in a single-phase system to introduce amino groups on their surface through the well-developed Au–S chemistry. Subsequently, amino groups of AuNPs were reacted with acyl chloride groups of GOS to form a novel hybrid material containing GOS and AuNPs. Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), energy dispersive X-ray (EDX) spectroscopy, ultraviolet–visible (UV–Vis) spectroscopy were used to study the changes in surface functionalities and demonstrate the successful immobilization of AuNPs on GOS surface. High resolution transmission electron microscopy (HR-TEM), field emission scanning electronic microscopy (FE-SEM), and atomic force microscopy (AFM) were employed to investigate the morphologies of prepared AuNPs and their distribution onto the GOS surface. Thermogravimetric analysis (TGA) was used to characterize the thermal stability of the samples on heating.