Auxiliary-Controlled Asymmetric [3+2]-Dipolar Cycloaddition of Azomethine Ylides Generated from Au-Catalyzed Intramolecular Redox Reaction of Nitronyl Alkynes

As strong as an aux: An electronically‐tuned hydroxylamine functions as an excellent chiral auxiliary for [3+2] cycloaddition of the azomethine ylides generated in‐situ from gold‐catalyzed redox reaction of alkynyl nitrones.

Saved in:
Bibliographic Details
Published in:Chemistry, an Asian journal an Asian journal, 2011-08, Vol.6 (8), p.1977-1981
Main Authors: Jeong, Jaewon, Yeom, Hyun-Suk, Kwon, Ohyun, Shin, Seunghoon
Format: Article
Language:English
Subjects:
[3+2] dipolar cycloaddition
Chemistry
chiral auxiliaries
gold
hydroxylamines
ylides
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:As strong as an aux: An electronically‐tuned hydroxylamine functions as an excellent chiral auxiliary for [3+2] cycloaddition of the azomethine ylides generated in‐situ from gold‐catalyzed redox reaction of alkynyl nitrones.
ISSN:1861-4728
1861-471X
DOI:10.1002/asia.201100159