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Exceptional high-temperature stability through distillation-like self-stabilization in bimetallic nanoparticles
Metal nanoparticles with precisely controlled size and composition are highly attractive for heterogeneous catalysis. However, their poor thermal stability remains a major hurdle on the way towards application at realistic technical conditions. Recent progress in this area has focused on nanostructu...
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Published in: | Nature materials 2010-01, Vol.9 (1), p.75-81 |
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Main Authors: | , |
Format: | Article |
Language: | English |
Subjects: | |
Citations: | Items that this one cites Items that cite this one |
Online Access: | Get full text |
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Summary: | Metal nanoparticles with precisely controlled size and composition are highly attractive for heterogeneous catalysis. However, their poor thermal stability remains a major hurdle on the way towards application at realistic technical conditions. Recent progress in this area has focused on nanostructured oxides to stabilize embedded metal nanoparticles. Here, we report an alternative approach that relies on synthesizing bimetallic nanoparticles with precise compositional control to obtain improved high-temperature stability. We find that PtRh nanoparticles with sufficiently high Rh content survive extended calcination at temperatures up to ∼850
∘
C without significant sintering. For lower Rh content, sacrificial self-stabilization of individual nanoparticles through a distillation-like process is observed: the low-melting-point metal (Pt) bleeds out and the increasing concentration of the high-melting-point metal (Rh) leads to re-stabilization of the remaining nanoparticle. This principle of thermal self-stabilization should be broadly applicable to the development of multi-metallic nanomaterials for a broad range of high-temperature applications.
Metal nanoparticles with controlled composition and size are attractive candidates for heterogeneous catalysis. Now, a distillation-like process is shown to result in the synthesis of bimetallic PtRh nanoparticles with precise compositional control and high temperature stability. |
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ISSN: | 1476-1122 1476-4660 |
DOI: | 10.1038/nmat2584 |