On the possibilities of high-resolution continuum source graphite furnace atomic absorption spectrometry for the simultaneous or sequential monitoring of multiple atomic lines

• Published in: Spectrochimica acta. Part B: Atomic spectroscopy 2011-05, Vol.66 (5), p.321-328
• Main Authors: Resano, M., Rello, L., Flórez, M., Belarra, M.A.
• Format: Article
• Language: English
• Subjects: Atomic absorption analysis; Cadmium; Continuums; Furnaces; Graphite; High-resolution continuum source graphite furnace atomic absorption spectrometry; Instrumentation; Internal standardization; Monitoring; Monitoring of multiplets; Multi-element analysis; Nickel; Solid sampling
• ISSN: 0584-8547; 1873-3565
• DOI: 10.1016/j.sab.2011.03.008

This paper explores the potential of commercially available high-resolution continuum source graphite furnace atomic absorption spectrometry instrumentation for the simultaneous or sequential monitoring of various atomic lines, in an attempt to highlight the analytical advantages that can be derived from this strategy. In particular, it is demonstrated how i) the monitoring of multiplets may allow for the simple expansion of the linear range, as shown for the measurement of Ni using the triplet located in the vicinity of 234.6 nm; ii) the use of a suitable internal standard may permit improving the precision and help in correcting for matrix-effects, as proved for the monitoring of Ni in different biological samples; iii) direct and multi-element analysis of solid samples may be feasible on some occasions, either by monitoring various atomic lines that are sufficiently close (truly simultaneous monitoring, as demonstrated in the determination of Co, Fe and Ni in NIST 1566a Oyster tissue) or, alternatively, by opting for a selective and sequential atomization of the elements of interest during every single replicate. Determination of Cd and Ni in BCR 679 White cabbage is attempted using both approaches, which permits confirming that both methods can offer very similar and satisfactory results. However, it is important to stress that the second approach provides more flexibility, since analysis is no longer limited to those elements that show very close atomic lines (closer than 0.3 nm in the ultraviolet region) with a sensitivity ratio similar to the concentration ratio of the analytes in the samples investigated.