Aqueous Electrochemistry of Poly(vinylanthraquinone) for Anode-Active Materials in High-Density and Rechargeable Polymer/Air Batteries

• Published in: Journal of the American Chemical Society 2011-12, Vol.133 (49), p.19839-19843
• Main Authors: Choi, Wonsung, Harada, Daisuke, Oyaizu, Kenichi, Nishide, Hiroyuki
• Format: Article
• Language: English
• Subjects: Air; Anthraquinones - chemistry; Electric Power Supplies; Electrochemical Techniques; Electrodes; Electrolytes - chemistry; Oxidation-Reduction; Vinyl Compounds - chemistry; Water - chemistry
• ISSN: 0002-7863; 1520-5126
• DOI: 10.1021/ja206961t

A layer of poly(2-vinylanthraquinone) on current collectors underwent reversible electrode reaction at −0.82 V vs Ag/AgCl in an aqueous electrolyte. A repeatable charging/discharging cycles with a redox capacity comparable to the formula weight-based theoretical density at the negative potential suggested that all of the anthraquinone pendants in the layer was redox-active, that electroneutralization by an electrolyte cation was accomplished throughout the polymer layer, and that the layer stayed on the current collector without exfoliation or dissolution into the electrolyte during the electrolysis. The charging/discharging behavior of the polymer layer in the aqueous electrolyte revealed the capability of undergoing electrochemistry even in the nonsolvent of the pendant group, which offered insight into the nature of the anthraquinone pendants populated on the aliphatic chain. Charging/discharging capability of air batteries was accomplished by using the polymer layer as an organic anode-active material. A test cell fabricated using the conventional MnO2/C cathode catalyst exhibited a discharging voltage at 0.63 V corresponding to their potential gap and a charging/discharging cycle of more than 500 cycles without loss of the capacity.