In-situ neutron radiography investigations of hydrogen diffusion and absorption in zirconium alloys

• Published in: Nuclear instruments & methods in physics research. Section A, Accelerators, spectrometers, detectors and associated equipment Accelerators, spectrometers, detectors and associated equipment, 2011-09, Vol.651 (1), p.253-257
• Main Authors: Grosse, M., van den Berg, M., Goulet, C., Lehmann, E., Schillinger, B.
• Format: Article
• Language: English
• Subjects: Calibration; Cross sections; Diffusion; Dissolution; Hydrogen; Hydrogen storage; Neutron radiography; Nuclear fuel rod cladding material; Oxides; Zirconium; Zirconium base alloys
• ISSN: 0168-9002; 1872-9576
• DOI: 10.1016/j.nima.2010.12.070

The fast and non-destructive character of neutron radiography provides the possibility of in-situ investigations of hydrogen uptake and diffusion in zirconium alloys. A special reaction furnace with neutron transparent windows was constructed. The method of quantitative hydrogen determination by neutron transmission measurements was calibrated for each experimental run. Additionally, oxygen is absorbed in the α-Zr phase and precipitated in the oxide layer. The calibration of the correlation between hydrogen and oxygen concentrations and total neutron cross-sections at room temperature and between 1123 and 1623 K are described. Results of in-situ neutron radiography investigations of hydrogen diffusion and absorption are presented in this paper. A linear dependence of the total macroscopic neutron cross section on the H/Zr atomic ratio as well as on the oxygen concentration was found. No significant temperature dependence of the total neutron cross-sections of hydrogen dissolved in β-Zr or oxygen dissolved in the α-Zr or precipitated in the oxide layer was found.