Adsorption of Zn(II) and Cd(II) ions in batch system by using the Eichhornia crassipes

• Published in: Water science and technology 2011-01, Vol.64 (9), p.1857-1863
• Main Authors: Módenes, A N, Espinoza-Quiñones, F R, Borba, C E, Trigueros, D E G, Lavarda, F L, Abugderah, M M, Kroumov, A D
• Format: Article
• Language: English
• Subjects: Adsorption; Aquatic plants; Batch Cell Culture Techniques - methods; Biodegradation, Environmental; Cadmium; Cadmium - isolation & purification; Eichhornia - metabolism; Eichhornia crassipes; Freshwater; Freshwater plants; Grain; Heavy metals; Ions; Isotherms; Kinetics; Models, Chemical; Removal; Sorption; Surface Properties; Temperature; Uptake; Zinc; Zinc - isolation & purification
• ISSN: 0273-1223; 1996-9732
• DOI: 10.2166/wst.2011.764

In this work, the displacement effects on the sorption capacities of zinc and cadmium ions of the Eichornia crassipes-type biosorbent in batch binary system has been studied. Preliminary single metal sorption experiments were carried out. An improvement on the Zn(II) and Cd(II) ions removal was achieved by working at 30 °C temperature and with non-uniform biosorbent grain sizes. A 60 min equilibrium time was achieved for both Zn(II) and Cd(II) ions. Furthermore, it was found that the overall kinetic data were best described by the pseudo second-order kinetic model. Classical multi-component adsorption isotherms have been tested as well as a modified extended Langmuir isotherm model, showing good agreement with the equilibrium binary data. Around 0.65 mequiv./g maximum metal uptake associated with the E. crassipes biosorbent was attained and the E. crassipes biosorbent has shown higher adsorption affinity for the zinc ions than for the cadmium ones in the binary system.