Thermally Stable Gold(I) Ethylene Adducts: [(HB{3,5-(CF₃)₂Pz}₃)Au(CH₂==CH₂)] and [(HB{3-(CF₃),5-(Ph)Pz}₃)Au(CH₂==CH₂)]

Captured by scorpionates: Using fluorinated scorpionates, remarkably stable gold(I) complexes containing ethylene are isolated and structurally characterized (see structure of molecule core: yellow Au, blue N, red B, light gray C). These adducts feature κ2‐bonded tris(pyrazolyl)borate ligands, and s...

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Bibliographic Details
Published in:Angewandte Chemie (International ed.) 2007-10, Vol.46 (41), p.7814-7816
Main Authors: Dias, H.V. Rasika, Wu, Jiang
Format: Article
Language:English
Subjects:
ethylene
gold
N ligands
structure elucidation
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