Nickel-catalyzed manipulation of tertiary phosphines via highly selective C–P bond cleavage

A catalytic cycle involving oxidative addition of nickel(0) with a carbon-carbon single bond in the three-membered ring of diarylmethylenecyclopropa[b]naphthalenes, highly selective cleavage of the C-P bond, and migration of the aryl group of phosphine consequently provides a new type of bulky phosp...

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) England), 2013-01, Vol.49 (70), p.7747-7749
Main Authors: Cao, Jian, Huang, Xian, Wu, Luling
Format: Article
Language:English
Subjects:
Aromatic compounds
Bonding
Carbon-carbon composites
catalytic activity
chemical bonding
chemical communication
chemical reactions
Cleavage
cleavage (chemistry)
Migration
moieties
naphthalenes
Nickel
phosphine
Phosphines
Rings (mathematics)
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