Direct Hydroboration of BB Bonds: A Mild Strategy for the Proliferation of BB Bonds

Synthetic access to electron‐precise boron chains is hampered by the preferential formation of nonclassical structures. The few existing strategies for this involve either strongly reducing reagents or transition‐metal catalysts, both with distinct disadvantages. The synthesis of new furyl‐ and thie...

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Bibliographic Details
Published in:Angewandte Chemie International Edition 2014-03, Vol.53 (12), p.3241-3244
Main Authors: Braunschweig, Holger, Dewhurst, Rian D., Hörl, Christian, Phukan, Ashwini K., Pinzner, Florian, Ullrich, Stefan
Format: Article
Language:English
Subjects:
Boron
Catalysis
Catalysts
Coupling agents
diborenes
Hydroboration
oxygen heterocycles
polyboranes
Reducing agents
Strategy
sulfur heterocycles
Synthesis
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