On the Reactivity of Silylated Ge 9 Clusters: Synthesis and Characterization of [ZnCp(Ge 9 Si(SiMe 3 ) 3 3 )], [CuP i Pr 3 (Ge 9 Si(SiMe 3 ) 3 3 )], and [(CuP i Pr 3 ) 4 Ge 9 (SiPh 3 ) 2 2 ]
We report on the synthesis of new derivatives of silylated clusters of the type [Ge 9 (SiR 3 ) 3 ] − (R = SiMe 3 , Me = CH 3 ; R = Ph, Ph = C 6 H 5 ) as well as on their reactivity towards copper and zinc compounds. The silylated cluster compounds were synthesized by heterogeneous reactions starting...
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| Published in: | Chemistry : a European journal 2016-12, Vol.22 (52), p.18794-18800 |
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| Main Authors: | , , |
| Format: | Article |
| Language: | English |
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| Online Access: | Get full text |
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