Between Localization and Delocalization: Ru(cod)2+ Units in the Zintl Clusters [Bi9Ru(cod)2]3− and [Tl2Bi6Ru(cod)]2

Reactions of [K(crypt‐222)]2(TlBi3)⋅0.5 en (1 b) with [Ru(cod)(H2CC(Me)CH2)2] (A) in 1,2‐diaminoethane (en) led to the formation of two compounds with new bismuth‐rich cluster anions, [K(crypt‐222)]3[Bi9Ru(cod)2]⋅1.5 en (2) and [K(crypt‐222)]2[Tl2Bi6Ru(cod)]⋅2 tol (3), alongside the salt of a binary...

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Bibliographic Details
Published in:	Angewandte Chemie International Edition 2017-10, Vol.56 (43), p.13253-13258
Main Authors:	Lichtenberger, Niels, Spang, Nils, Eichhöfer, Andreas, Dehnen, Stefanie
Format:	Article
Language:	English
Subjects:	Anions bismuth Bismuth compounds bonding Chemical bonds Cluster analysis Intermediates Ionization Ions Ligands Localization Mass spectrometry Mass spectroscopy Quantum chemistry ruthenium thallium Zintl clusters
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