Base‐Mediated Defluorosilylation of C(sp2)−F and C(sp3)−F Bonds

The ability to selectively forge C–heteroatom bonds by C−F scission is typically accomplished by metal catalysts, specialized ligands and/or harsh reaction conditions. Described herein is a base‐mediated defluorosilylation of unactivated C(sp2)−F and C(sp3)−F bonds that obviates the need for metal c...

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Bibliographic Details
Published in:Angewandte Chemie International Edition 2019-02, Vol.58 (7), p.2064-2068
Main Authors: Liu, Xiang‐Wei, Zarate, Cayetana, Martin, Ruben
Format: Article
Language:English
Subjects:
Bonding
Catalysis
Catalysts
Cleavage
cross-coupling
fluorine
reaction mechanisms
silylation
synthetic methods
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