Tackling Capacity Fading in Vanadium Redox Flow Batteries with Amphoteric PBI/Nafion Bilayer Membranes

Vanadium flow batteries are among the most promising technologies for stationary energy storage applications if their cost of storage can be further decreased. Capacity fading resulting from imbalanced vanadium crossover is a key operating cost component. We report a new approach to avoid this cost...

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Bibliographic Details
Published in:ChemSusChem 2019-04
Main Authors: Oldenburg, Fabio Jonas, Nilsson, Elisabeth, Schmidt, Thomas Justus, Gubler, Lorenz
Format: Article
Language:English
Online Access:Get full text
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Summary:Vanadium flow batteries are among the most promising technologies for stationary energy storage applications if their cost of storage can be further decreased. Capacity fading resulting from imbalanced vanadium crossover is a key operating cost component. We report a new approach to avoid this cost by balancing electrolyte transport with amphoteric bilayer Nafion®/meta-polybenzimidazole membranes. Within this system, the anion- and cation exchange capacity can be tuned in straightforward manner via the thickness of the respective polymer layer to balance electrolyte transport for a given current density. At high current densities a net migrative flux of vanadium directed towards the positive side is observed due to the higher average charge of vanadium ions present at the negative side. The coulombic repulsion between the vanadium ions and the positive charges in the membrane counteracts this migrative transport and is able to reverse the direction of the net vanadium flux. For a technically relevant current density of 120 mA cm-2, a PBI thickness of 3-4 µm is required to balance the vanadium crossover and to minimize capacity fading.
ISSN:1864-564X