A Scandium Metalloligand‐Based Heterobimetallic Pd−Sc Complex: Electronic Tuning Through a Very Short Pd→Sc Dative Bond

The first heterobimetallic Pd−Sc complex featuring a very short Pd→Sc dative bond has been synthesized and characterized by multinuclear NMR spectroscopy, X‐ray diffraction analysis, and electrochemistry. Computational studies elucidated the nature of the Pd→Sc bond as a donor–acceptor interaction,...

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Bibliographic Details
Published in:Chemistry : a European journal 2019-08, Vol.25 (43), p.10149-10155
Main Authors: Du, Jun, Huang, Zeming, Zhang, Yanan, Wang, Shaowu, Zhou, Shuangliu, Fang, Huayi, Cui, Peng
Format: Article
Language:English
Subjects:
Carbon monoxide
Chemistry
Computer applications
Electrochemistry
Magnetic resonance spectroscopy
metalloligands
metal–metal interactions
NMR
NMR spectroscopy
Nuclear magnetic resonance
Palladium
rare earths
Scandium
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