Effect of cytosine-Ag-cytosine base pairing on the redox potential of the Ag/Ag couple and the chemical reduction of Ag to Ag by tetrathiafulvalene

The redox properties of metallo-base pairs remain to be elucidated. Herein, we report the detailed 1 H/ 13 C/ 109 Ag NMR spectroscopic and cyclic voltammetric characterisation of the [Ag(cytidine) 2 ] + complex as isolated cytosine-Ag + -cytosine (C-Ag + -C) base pairs. We also performed comparative...

Full description

Saved in:
Bibliographic Details
Published in:Dalton transactions : an international journal of inorganic chemistry 2021-06, Vol.5 (22), p.7633-7639
Main Authors: Dairaku, Takenori, Kawai, Rika, Kanaba, Teppei, Ono, Tetsuya, Yoshida, Kentaro, Sato, Hajime, Nozawa-Kumada, Kanako, Kondo, Yoshinori, Kondo, Jiro, Ono, Akira, Tanaka, Yoshiyuki, Kashiwagi, Yoshitomo
Format: Article
Language:English
Subjects:
Chemical reduction
Comparative studies
Electrode potentials
Metallography
Nanoparticles
NMR
Nuclear magnetic resonance
Nucleosides
Redox reactions
Silver
Voltammetry
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!