Decatungstate-Catalyzed C(sp 3)–H Sulfinylation: Rapid Access to Diverse Organosulfur Functionality

Here we report the direct conversion of strong, aliphatic C­(sp 3)–H bonds into the corresponding alkyl sulfinic acids via decatungstate photocatalysis. This transformation has been applied to a diverse range of C­(sp 3)-rich scaffolds, including natural products and approved pharmaceuticals, provid...

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Bibliographic Details
Published in:Journal of the American Chemical Society 2021-07, Vol.143 (26), p.9737-9743
Main Authors: Sarver, Patrick J, Bissonnette, Noah B, MacMillan, David W. C
Format: Article
Language:English
Subjects:
Anilides - chemistry
Biological Products - chemistry
Catalysis
drugs
Molecular Structure
Nitriles - chemistry
photocatalysis
Photochemical Processes
Sulbactam - chemistry
sulfinic acids
Sulfinic Acids - chemistry
Thermodynamics
Tosyl Compounds - chemistry
Tryptamines - chemistry
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