Enhancing the oxygen evolution reaction of cobalt hydroxide by fabricating nanocomposites with fluorine-doped graphene oxide

• Published in: Dalton transactions : an international journal of inorganic chemistry 2023-03, Vol.52 (12), p.3877-3883
• Main Authors: Muthukumar, Pandi, Nantheeswaran, Periyappan, Mariappan, Mariappan, Pannipara, Mehboobali, Al-Sehemi, Abdullah G, Anthony, Savarimuthu Philip
• Format: Article
• Language: English
• Subjects: Catalysts; Charge transfer; Chemical synthesis; Cobalt; Current density; Electrocatalysts; Electronegativity; Fluorine; Graphene; Interface stability; Nanocomposites; Nanoparticles; Nitrogen; Oxygen evolution reactions; Photoelectrons; Reaction kinetics; X ray photoelectron spectroscopy
• ISSN: 1477-9226; 1477-9234
• DOI: 10.1039/d2dt04169c

Fluorine and nitrogen codoped cobalt hydroxide-graphene oxide nanocomposites (N,F-Co(OH) 2 /GO) were synthesized by a simple hydrothermal method and demonstrated highly enhanced oxygen evolution activity in an alkaline medium. N,F-Co(OH) 2 /GO synthesized under optimized reaction conditions required an overpotential of 228 mV to produce the benchmark current density of 10 mA cm −2 (scan rate 1 mV s −1 ). In contrast, N,F-Co(OH) 2 without GO and Co(OH) 2 /GO without fluorine required higher overpotentials (370 (N,F-Co(OH) 2 ) and 325 mV (Co(OH) 2 /GO)) for producing the current density of 10 mA cm −2 . The low Tafel slope (52.6 mV dec −1 ) and charge transfer resistance, and high electrochemical double layer capacitance of N,F-Co(OH) 2 /GO compared to N,F-Co(OH) 2 indicate faster kinetics at the electrode-catalyst interface. The N,F-Co(OH) 2 /GO catalyst showed good stability over 30 h. High-resolution transmission electron microscope (HR-TEM) images showed good dispersion of polycrystalline Co(OH) 2 nanoparticles in the GO matrix. X-ray photoelectron spectroscopic (XPS) analysis revealed the coexistence of Co 2+ /Co 3+ and the doping of nitrogen and fluorine in N,F-Co(OH) 2 /GO. XPS further revealed the presence of F in its ionic state and being covalently attached to GO. The integration of highly electronegative F with GO stabilizes the Co 2+ active centre along with improving the charge transfer and adsorption process that contributes to improved OER. Thus, the present work reports a facile method for preparing F-doped GO-Co(OH) 2 electrocatalysts with enhanced OER activity under alkaline conditions. The integration of electronegative F into graphene oxide improves the charge-transfer kinetics and stability of the Co 2+ active center and showed enhanced OER activity.