La n(n+1)+x Ni n(n+5)+y Si(n+1)(n+2)–z : A Symmetric Mirror Homologous Series in the La–Ni–Si System

A series of four homologous silicides have been discovered during systematic explorations in the central part of the La–Ni–Si system at 1000 °C. All compounds La12.5Ni28.0Si18.3 (n = 3; a = 28.8686(8), c = 4.0737(2) Å, Z = 3), La22.1Ni39.0Si27.8 (n = 4; a = 20.9340(6), c = 4.1245(2) Å, Z = 1), La32....

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Published in:Inorganic chemistry 2023-07, Vol.62 (27), p.10736-10742
Main Authors: Grilli, Davide, Smetana, Volodymyr, Ahmed, Sheikh J., Shtender, Vitalii, Pani, Marcella, Manfrinetti, Pietro, Mudring, Anja-Verena
Format: Article
Language:English
Online Access:Get full text
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