Discrete Mono-, Di-, and Trinuclear Anions [MoOF 5 ] − , [Mo V OF 5 ] 2– , [MoO 2 F 4 ] 2– , [Mo 2 O 2 F 9 ] − , [Mo 3 O 3 F 13 ] − , and the Infinite Chain Anion [MoO 2 F 3 ] − Obtained from Reactions of MoOF 4 : Synthesis and Analysis of the Structure-Chemical Relations of the Compounds
The herein-reported oxyfluoridometallate salts were synthesized and structurally characterized during the studies of the Lewis acidity of OF ( = Mo, W) with various fluoride ion donors (RbF, CsF, TlF, AgF, SrF , BaF , PbF ) in different solvents (aqHF 48%, aHF, BrF , ClF ). Phase-pure MoOF was eithe...
Saved in:
| Published in: | Inorganic chemistry 2023-08, Vol.62 (33), p.13435-13452 |
|---|---|
| Main Authors: | , , , , |
| Format: | Article |
| Language: | English |
| Citations: | Items that this one cites |
| Online Access: | Get full text |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|