C(sp2)─H Bond Activation with a Heterometallic Nickel–Aluminium Complex

Herein we present a ligand‐catalyzed bond‐breaking and making process that occurs with a Ni–Al heterometallic complex. While combinations of Ni pre‐catalysts and Al additives are known for site‐selective C─H functionalization, detailed studies of such systems are rare. Combining [Ni(COD)2] and [(BDI...

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Bibliographic Details
Published in:Angewandte Chemie International Edition 2025-09, Vol.64 (36), p.e202512684-n/a
Main Authors: Zurakowski, Joseph A., Stadler, Benedek, Drover, Marcus W., Crimmin, Mark R.
Format: Article
Language:English
Subjects:
Aluminum
Catalysis
Catalysts
C─H activation
Heavy metals
Heterometallic complex
Hydrogen evolution
Ligands
Nickel
Phosphine
Phosphines
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