Bi(III) Ion Electroreduction in the Presence of Ethanol and Sodium 1‐Octanesulfonate at a Thin‐Layer Amalgam Electrode (Renewable Liquid Silver Amalgam Film Electrode); Kinetic and Thermodynamic Aspects

This study investigates the Bi(III) ions electroreduction in aqueous chlorate(VII) and aqueous‐ethanolic chlorate(VII)‐supporting electrolytes (SE) in the presence of the anionic surfactant sodium 1‐octanesulfonate (1OSASS) over a range of temperatures. Electrochemical techniques, including direct c...

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Bibliographic Details
Published in:Chemphyschem 2026-02, Vol.27 (3), p.e202500518-n/a
Main Authors: Pawlak, Alicja Natalia, Nosal‐Wiercińska, Agnieszka
Format: Article
Language:English
Subjects:
Activation energy
activation parameters
bismuth(III) electroreduction
cap‐pair effect
Diffusion coefficient
Diffusion rate
Direct current
Electrodes
Electrolytes
Electron transfer
Electrowinning
Enthalpy
Ethanol
Gibbs free energy
Kinetics
mixed solvent systems
Parameters
Polarography
Sodium
surfactant inhibition
Surfactants
Thermodynamics
Voltammetry
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