Tailoring a hierarchical porous carbon electrode from carbon black via 3D diatomite morphology control for enhanced electrochemical performance

• Published in: Nanoscale advances 2024-09
• Main Authors: Appiah, Eugene Sefa, Mensah-Darkwa, Kwadwo, Andrews, Anthony, Agyemang, Frank Ofori, Nartey, Martinson Addo, Makgopa, Katlego, Hou, Yongdan, Aggrey, Patrick, Quansah, David Ato
• Format: Article
• Language: English
• Subjects: Chemistry
• ISSN: 2516-0230; 2516-0230
• DOI: 10.1039/d4na00680a

Carbon black, a nano-porous material usually derived from the pyrolysis of waste tyres possesses varied particle sizes and morphology making it a viable material for several engineering applications. However, the high tendency for CB to agglomerate remains a challenge. To address this, bio-templating has been employed to produce a nanostructured porous carbon electrode material for supercapacitor applications using diatomite as a template. Diatomite-synthesized activated carbon (DSAC) was fabricated through a three-step process involving acid treatment of diatomite, thermal activation of carbon black, and bio-template synthesis. The resulting material was thoroughly characterized using XRD, Raman spectroscopy, BET analysis, and SEM imaging. Its electrochemical properties were assessed through cyclic voltammetry, galvanostatic charge-discharge, and electrochemical impedance spectroscopy. The DSAC material exhibited a high specific surface area of 266.867 m g , pore volume of 0.6606 cm g , and mean pore radius of 1.8943 nm. The electrochemical evaluation revealed that DSAC demonstrates excellent electrochemical performance, achieving a high specific capacitance of 630.18 F g and retaining 94.29% capacitance after 5000 cycles at 1 A g . The DSAC electrode is eco-friendly and a promising candidate for supercapacitor applications.