New Way of Direct Nitrogen Atom Phenylation in Quinoline Derivatives

Comparison of ion-molecular reactions of free-phenyl cations generated by tritium β-decay with 2-methyl- and 2-phenylquinolines has been investigated. The reaction of direct nitrogen atom phenylation with the help of nucleogenic phenyl cations has been fulfilled for the first time and a new one-step...

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Published in:ISRN Organic Chemistry 2012-07, Vol.2012, p.1-4
Main Authors: Shchepina, Nadezhda E., Avrorin, Viktor V., Badun, Gennady A., Lewis, Scott B., Shurov, Sergey N.
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description Comparison of ion-molecular reactions of free-phenyl cations generated by tritium β-decay with 2-methyl- and 2-phenylquinolines has been investigated. The reaction of direct nitrogen atom phenylation with the help of nucleogenic phenyl cations has been fulfilled for the first time and a new one-step synthesis of tritium-labeled N-phenyl-2-phenylquinolinium salt—lipophilic radioactive biological marker has been elaborated.
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title New Way of Direct Nitrogen Atom Phenylation in Quinoline Derivatives
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