Cross-Coupling of Remote meta-C–H Bonds Directed by a U‑Shaped Template

meta-C–H arylation and methylation of 3-phenylpropanoic acid and phenolic derivatives were developed using an easily removable nitrile template. The combination of a weakly coordinating U-shaped template and mono-protected amino acid ligand was crucial for the cross-coupling of C–H bonds with organo...

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Bibliographic Details
Published in:Journal of the American Chemical Society 2013-12, Vol.135 (48), p.18056-18059
Main Authors: Wan, Li, Dastbaravardeh, Navid, Li, Gang, Yu, Jin-Quan
Format: Article
Language:English
Subjects:
amino acids
Boron Compounds - chemistry
chemical bonding
Communication
ligands
Methylation
Nitriles - chemistry
Palladium - chemistry
Phenols - chemistry
Phenylpropionates - chemistry
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