Nonenzymatic enantioselective synthesis of all-carbon quaternary centers through desymmetrization

[Display omitted] The asymmetric desymmetrization of meso or prochiral compounds containing an all-carbon quaternary center is an attractive alternative to classical synthetic approaches aimed at the asymmetric formation of a new C–C bond. This review focuses on nonenzymatic desymmetrizations that u...

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Published in:Tetrahedron letters 2015-11, Vol.56 (47), p.6523-6535
Main Author: Petersen, Kimberly S.
Format: Article
Language:English
Subjects:
All-carbon quaternary center
Asymmetric
Desymmetrization
Organocatalysis
Transition-metal catalysis
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description [Display omitted] The asymmetric desymmetrization of meso or prochiral compounds containing an all-carbon quaternary center is an attractive alternative to classical synthetic approaches aimed at the asymmetric formation of a new C–C bond. This review focuses on nonenzymatic desymmetrizations that utilize transition metal catalysts or organocatalysts to distinguish between enantiotopic groups to generate enantioenriched compounds containing all-carbon quaternary stereocenters.
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source ScienceDirect Journals
subjects All-carbon quaternary center
Asymmetric
Desymmetrization
Organocatalysis
Transition-metal catalysis
title Nonenzymatic enantioselective synthesis of all-carbon quaternary centers through desymmetrization
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