Synthesis, Structural Characterization, and DFT Investigations of [M x M′5–x Fe4(CO)16]3– (M, M′ = Cu, Ag, Au; M ≠ M′) 2‑D Molecular Alloy Clusters

Miscellaneous 2-D molecular alloy clusters of the type [M x M′5–x Fe4(CO)16]3– (M, M′ = Cu, Ag, Au; M ≠ M′) have been prepared through the reactions of [Cu3Fe3(CO)12]3–, [Ag4Fe4(CO)16]4– or [M5Fe4(CO)16]3– (M = Cu, Ag) with M′(I) salts (M′ = Cu, Ag, Au). Their formation involves a combination of oxi...

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Published in:Inorganic chemistry 2020-11, Vol.59 (21), p.15936-15952
Main Authors: Berti, Beatrice, Bortoluzzi, Marco, Cesari, Cristiana, Femoni, Cristina, Iapalucci, Maria Carmela, Soleri, Leonardo, Zacchini, Stefano
Format: Article
Language:English
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