Simultaneous removal of SO2 and NOx from flue gas by low-temperature adsorption over activated carbon

• Published in: Scientific reports 2021-05, Vol.11 (1), p.11003-11003, Article 11003
• Main Authors: Wang, Shiqing, Xu, Shisen, Gao, Shiwang, Xiao, Ping, Jiang, Minhua, Zhao, He, Huang, Bin, Liu, Lianbo, Niu, Hongwei, Wang, Jinyi, Guo, Dongfang
• Format: Article
• Language: English
• Subjects: 639/4077; 704/172; Activated carbon; Adsorption; Carbon; Catalytic oxidation; Cold; Emissions; Flow rates; Flue gas; Humanities and Social Sciences; Low temperature; multidisciplinary; Nitrogen dioxide; Oxidation; Oxygen; Science; Science (multidisciplinary); Specific capacity; Sulfur dioxide
• ISSN: 2045-2322; 2045-2322
• DOI: 10.1038/s41598-021-90532-9

An exceptional phenomenon has been observed that SO 2 and NO x in flue gas can be effectively adsorbed over activated carbon with a surprising capacity at cold temperatures with the presence of oxygen. In this study, the adsorption characteristics of NO and SO 2 over activated carbon at 80, 20, 0, and − 20 is experimentally investigated. Without the presence of oxygen, adsorption of NO is negligible. In the presence of oxygen, NO can be oxidized to NO 2 over activated carbon which leads to the co-adsorption of NO/NO 2 within the adsorption bed. Catalytic oxidation of NO over activated carbon can be significantly enhanced at cold temperatures, leading to an extraordinary increase of adsorption capacity of NO. With an initial concentration of NO = 200 ppmv and a space velocity of 5000 h −1 , the average specific capacity increases from 3.8 to 169.1 mg/g when the temperature decreases from 80 to – 20 ℃. For NO–O 2 co-adsorption, the specific capacity increases along the adsorption bed due to the increasing NO 2 concentrations. The adsorption capacity of SO 2 is also significantly enhanced at cold temperatures. With an initial concentration of SO 2  = 1000 ppmv, the specific capacity increases from 12.9 to 123.1 mg/g when the temperature decreases from 80 to – 20 ℃. A novel low-temperature adsorption (LAS) process is developed to simultaneously remove SO 2 and NO x from flue gas with a target of near-zero emission. A pilot-scale testing platform with a flue gas flowrate of 3600 Nm 3 /h is developed and tested. Emission of both SO 2 and NO x is less than 1 ppmv, and the predicted energy penalty is about 3% of the net generation.