Viscosities of electrolyte solutions

The effect of solute–solvent interactions on the viscosity of dilute electrolyte solutions is considered in terms of the solute contribution to the activation free energy, enthalpy or entropy, for viscous flow. Two classes of electrolyte are considered, those involving inorganic ions and those invol...

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Bibliographic Details
Published in:Philosophical transactions of the Royal Society of London. Series A: Mathematical, physical, and engineering sciences physical, and engineering sciences, 2001-08, Vol.359 (1785), p.1529-1543
Main Authors: Symons, M. C. R., Earle Waghorne, W.
Format: Article
Language:English
Subjects:
Aqueous Solutions
B-coefficient
Cations
Coefficient
Electrolytes
Free energy
Halides
Hydrophobic
Ions
Molecules
Non-Aqueous Solvents
Solutes
Solvation
Solvents
Viscosity
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Summary:The effect of solute–solvent interactions on the viscosity of dilute electrolyte solutions is considered in terms of the solute contribution to the activation free energy, enthalpy or entropy, for viscous flow. Two classes of electrolyte are considered, those involving inorganic ions and those involving larger organic ions such as the tetraalkylammonium salts.
ISSN:1364-503X
1471-2962
DOI:10.1098/rsta.2001.0864