A practical anodic oxidation of aminofurazans to azofurazans: an environmentally friendly routeElectronic supplementary information (ESI) available. CCDC 1007707 and 1007708. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c5ra05726d

Nickel oxyhydroxide, NiOOH, anode has been shown to be an effective tool for the oxidation of aminofurazans to azofurazans in ca. 1% aqueous alkali at room temperature. The electrochemical reaction is simple and convenient, eliminating the use of expensive and toxic organic or inorganic oxidants. Th...

Full description

Saved in:
Bibliographic Details
Main Authors: Sheremetev, Aleksei B, Lyalin, Boris V, Kozeev, Andrei M, Palysaeva, Nadezhda V, Struchkova, Marina I, Suponitsky, Kyrill Yu
Format: Article
Language:English
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:Nickel oxyhydroxide, NiOOH, anode has been shown to be an effective tool for the oxidation of aminofurazans to azofurazans in ca. 1% aqueous alkali at room temperature. The electrochemical reaction is simple and convenient, eliminating the use of expensive and toxic organic or inorganic oxidants. The green economic preparation of desired azo compounds is very clean, producing only H 2 as a result of cathodic reduction. Nickel oxyhydroxide anode is effective green tools for the electrooxidation of aminofurazans to azofurazans in ca . 1% aqueous NaOH at 20 °C. The reaction is simple and convenient, eliminating the use of expensive and toxic organic or inorganic oxidants.
ISSN:2046-2069
DOI:10.1039/c5ra05726d