The influence of stereochemistry on the reactivity of the Diels-Alder cycloaddition and the implications for reversible network polymerization

A detailed calorimetric investigation is performed on the influence of the stereochemistry of the furan-maleimide Diels-Alder reaction on the kinetics of the reversible network formation, in the absence of solvents. Two stereoisomers are formed, with the endo isomer forming kinetically faster and un...

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Bibliographic Details
Published in:Polymer chemistry 2019-01, Vol.1 (4), p.473-485
Main Authors: Cuvellier, Audrey, Verhelle, Robrecht, Brancart, Joost, Vanderborght, Bram, Van Assche, Guy, Rahier, Hubert
Format: Article
Language:English
Subjects:
Cycloaddition
Diels-Alder reactions
Network formation
NMR spectroscopy
Polymer chemistry
Rate constants
Reaction kinetics
Stereochemistry
Thermodynamic properties
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