Rational understanding of the catalytic mechanism of molybdenum carbide in polysulfide conversion in lithium-sulfur batteries

Lithium-sulfur (Li-S) batteries are promising candidates for next-generation energy storage devices due to their high theoretical energy density and whose practical applications are mainly hampered by the shuttle effect of intermediate polysulfides (LiPSs). Anchoring materials, such as β-Mo 2 C, wit...

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Bibliographic Details
Published in:Journal of materials chemistry. A, Materials for energy and sustainability Materials for energy and sustainability, 2020-06, Vol.8 (23), p.11818-11823
Main Authors: Sun, Mingzhu, Wang, Zhao, Li, Xue, Li, Haibo, Jia, Hongsheng, Xue, Xiangxin, Jin, Ming, Li, Jiaqi, Xie, Yu, Feng, Ming
Format: Article
Language:English
Subjects:
Anchoring
Catalysts
Catalytic converters
Chemical bonds
Chemical reactions
Conversion
Electrochemical analysis
Electrochemistry
Energy storage
Flux density
Lithium
Lithium sulfur batteries
Metal surfaces
Molybdenum
Molybdenum carbide
Polysulfides
Storage batteries
Sulfur
Sulfurization
X-ray spectroscopy
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Summary:Lithium-sulfur (Li-S) batteries are promising candidates for next-generation energy storage devices due to their high theoretical energy density and whose practical applications are mainly hampered by the shuttle effect of intermediate polysulfides (LiPSs). Anchoring materials, such as β-Mo 2 C, with strong chemical interaction has been proposed to improve the electrochemical performance of Li-S batteries. However, the chemical bonding and conversion reaction of LiPSs on the Mo 2 C surface are not well studied. Here, we report on the discovery that the superior performance of Mo 2 C originates from the sulfur termination. By combining X-ray spectroscopy measurements and theoretical calculations, we reveal that sulfur can passivate the Mo 2 C (101) surface, which not only offers moderate chemical interaction with LiPSs but also facilitates the conversion reactions during both the discharge and charge processes. Our results suggest that it is important to consider the sulfurization of catalysts with metal surfaces when they are used to accelerate the conversion of polysulfides. The S-passivated Mo 2 C behaves like a transition metal sulfide with strong binding to LiPSs, a small LiPS conversion energy barrier, and a low Li 2 S decomposition barrier.
ISSN:2050-7488
2050-7496
DOI:10.1039/d0ta01217c