New approaches to the functionalization of the 1-carba--decaborate anion

Two new approaches to the functionalization of the 1-carba- closo -decaborate anion [1-CB 9 H 10 ] − at boron atoms via the ring-opening of its 1,4-dioxane derivative with various nucleophiles and Pd-catalysed cross-coupling of its iodo derivative with aromatic amines and heteroaromatics were develo...

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Published in:Chemical communications (Cambridge, England) England), 2022-03, Vol.58 (23), p.3775-3778
Main Authors: Shmal'ko, Akim V, Cendoya, Paula, Anufriev, Sergey A, Suponitsky, Kyrill Yu, Gabel, Detlef, Sivaev, Igor B
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Summary:Two new approaches to the functionalization of the 1-carba- closo -decaborate anion [1-CB 9 H 10 ] − at boron atoms via the ring-opening of its 1,4-dioxane derivative with various nucleophiles and Pd-catalysed cross-coupling of its iodo derivative with aromatic amines and heteroaromatics were developed. Two new approaches to the functionalization of the 1-carba- closo -decaborate anion resulting in the formation of B-O and B-N bonds were developed.
ISSN:1359-7345
1364-548X
DOI:10.1039/d1cc06395b