Synthesis of -benzyl benzamides NaH-mediated aryne insertion into -sulfonylacetimidates

o -Benzylbenzoic acid derivatives are valuable synthetic intermediates, but conventional syntheses suffer from limited functional group tolerance and dependence on transition metals. Herein, we report a NaH-mediated strategy for preparing o -benzyl benzamides via regioselective aryne insertion into...

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Published in:Organic & biomolecular chemistry 2025-10, Vol.23 (41), p.9449-9454
Main Authors: Zhu, Zitong, Chen, Zhijian, Qian, Pengfei, Li, Ziyu, Zhang, Shilei, Luo, Fan
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